Abstract:
Conventional gas drainage in low-permeability coal seams is limited by low extraction efficiency and a rapid decline in gas concentration. Injecting CO
2 or N
2 to displace CH
4 can improve methane desorption and recovery, but the changing roles of pressure-driven drainage and desorption enhancement at different methane-content stages remain unclear. In this study, multi-cycle displacement and adsorption experiments were conducted on gas-bearing anthracite particles using CO
2 and N
2. Gas chromatography and the SRK real-gas equation of state were used to analyze tail-gas composition, CH
4 release behavior, and the occurrence state of the injected gases. The results show that after twelve displacement cycles, the CH
4 volume fraction in the tail gas decreased from 69.8% to 11.3% in the CO
2 group and from 64.5% to 13.4% in the N
2 group, with both groups showing clear staged declines. Because N
2 has weak adsorption affinity, it mainly remains in a free state and helps maintain relatively high pore pressure, resulting in stronger pressure-driven drainage. As a result, the final residual CH
4 proportion in the coal samples decreased to 52.0%, and the initial CH
4 release volume was 2.7 times that of the CO
2 group. In contrast, CO
2 is more strongly adsorbed, allowing it to enter and remain in coal matrix micropores. This led to a higher residual CH
4 proportion of 63.2% but also increased the total adsorbed gas content in the coal. Based on these findings, a staged gas-injection strategy is proposed. N
2 injection should be used in the early stage to accelerate gas drainage and maintain coal permeability, while CO
2 injection should be applied in the later stage to displace micropore-adsorbed CH
4 more deeply and support geological CO
2 storage.