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二元气体多循环深度置换下瓦斯促排效果研究

Gas drainage enhancement by multi-cycle deep displacement of binary gases

  • 摘要: 低渗煤层常规瓦斯抽采效率低、浓度衰减快,注入CO2或N2置换CH4是强化瓦斯促排的重要途径,但不同CH4含量阶段增压促排与促进解吸效应的演化关系尚不明确。以含瓦斯无烟煤颗粒为研究对象,开展CO2和N2多循环深度置换吸附实验,结合气相色谱测试、Soave-Redlich-Kwong(SRK)状态方程,分析尾气组分、CH4释放及注入气体赋存特征。实验结果表明,经过12次置换循环后,CO2组尾气CH4体积分数由69.8%降至11.3%,N2组由64.5%降至13.4%,均表现出明显的阶段性下降特征;N2弱吸附性使其更多以游离态赋存,可维持较高孔隙压力,表现出更强的增压促排能力,最终将样品残余CH4比例降至52.0%,置换初期CH4释放体积约为CO2组的2.7倍。相比之下,CO2强吸附性使其更易进入煤基质微孔并形成吸附滞留,样品残余CH4比例为63.2%,但其可提高煤体吸附态气体总量。提出了以前期N2快速促排并维持煤体渗透率、后期CO2深度置换微孔CH4与封存为核心的分阶段注气思路。

     

    Abstract: Conventional gas drainage in low-permeability coal seams is limited by low extraction efficiency and a rapid decline in gas concentration. Injecting CO2 or N2 to displace CH4 can improve methane desorption and recovery, but the changing roles of pressure-driven drainage and desorption enhancement at different methane-content stages remain unclear. In this study, multi-cycle displacement and adsorption experiments were conducted on gas-bearing anthracite particles using CO2 and N2. Gas chromatography and the SRK real-gas equation of state were used to analyze tail-gas composition, CH4 release behavior, and the occurrence state of the injected gases. The results show that after twelve displacement cycles, the CH4 volume fraction in the tail gas decreased from 69.8% to 11.3% in the CO2 group and from 64.5% to 13.4% in the N2 group, with both groups showing clear staged declines. Because N2 has weak adsorption affinity, it mainly remains in a free state and helps maintain relatively high pore pressure, resulting in stronger pressure-driven drainage. As a result, the final residual CH4 proportion in the coal samples decreased to 52.0%, and the initial CH4 release volume was 2.7 times that of the CO2 group. In contrast, CO2 is more strongly adsorbed, allowing it to enter and remain in coal matrix micropores. This led to a higher residual CH4 proportion of 63.2% but also increased the total adsorbed gas content in the coal. Based on these findings, a staged gas-injection strategy is proposed. N2 injection should be used in the early stage to accelerate gas drainage and maintain coal permeability, while CO2 injection should be applied in the later stage to displace micropore-adsorbed CH4 more deeply and support geological CO2 storage.

     

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