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环境压力对煤中甲烷扩散动力学特性的影响

Study on the impact of environmental pressure on the diffusion kinetic characteristics of CH4 in coal

  • 摘要: 为探究环境压力对煤中甲烷(CH4)扩散动力学特性的影响,选取高、中、低3种典型变质程度煤样,测定其在标准大气压(常压)及高于大气压环境下的CH4解吸特性,并基于单孔扩散模型获得扩散系数。结合3种煤的大分子结构模型,采用分子模拟方法,研究了环境压力对瓦斯扩散动力学特性的影响。结果表明,煤中CH4解吸过程符合改进的Langmuir EXT模型,拟合系数达0.99以上;环境压力从大气压增至0.20 MPa,显著抑制了CH4的解吸与扩散,极限解吸量最大降幅达32.48%;扩散系数随环境压力升高而减小,且降幅与煤孔隙结构相关。CH4的自扩散系数、校正扩散系数和传递扩散系数均随环境压力升高而下降,与实验结果一致。该研究揭示了环境压力抑制CH4解吸-扩散过程的作用机制,可为瓦斯扩散理论的完善及瓦斯灾害防治提供理论基础。

     

    Abstract: The influence of environmental pressure on the diffusion kinetic characteristics of methane in coal is investigated. Three typical coal samples with high, medium, and low degrees of metamorphism are selected, and the CH4 desorption characteristics under standard atmospheric pressure and above atmospheric pressure are measured. The diffusion coefficient is obtained based on the single-pore diffusion model. Furthermore, using the macromolecular structure models of coals, the influence of environmental pressure on the diffusion kinetic characteristics is simulated. The results show that the CH4 desorption process conforms to the Langmuir EXT model, with a fitting coefficient of over 0.99. When environmental pressure increases from atmospheric pressure to 0.20 MPa, the desorption and diffusion of CH4 are significantly inhibited, and the maximum reduction in the ultimate desorption amount reaches 32.48%. The diffusion coefficient decreases with the increase in environmental pressure, and the reduction extent correlates with the pore structure characteristics of the coal. The self-diffusion coefficient, corrected diffusion coefficient, and transfer diffusion coefficient of CH4 all decrease with the increase in environmental pressure, which is consistent with the experimental trend. This study reveals the mechanism of the effect of environmental pressure on inhibiting the CH4 desorption-diffusion process, and the research results can provide a theoretical basis for the improvement of the gas diffusion theory and the prevention and control of gas disasters.

     

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