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纳米流体作用下高阶煤润湿特性研究

Study on wetting characteristics of high-rank coal treated with nanofluids

  • 摘要: 为深入分析纳米流体对高阶煤润湿特性的影响,提高煤层注水技术的降尘效果。以山西晋城天地王坡煤矿和河南新乡赵固二矿高阶煤为研究对象,通过接触角实验探究SiO2纳米流体对煤体润湿性的影响;利用低场核磁共振设备,开展煤样在不同质量分数SiO2纳米流体作用下的核磁共振CPMG序列测试。结果表明:当纳米流体质量分数为1.50%时,对煤体润湿性的改善效果最好。纳米流体可显著增强水分在煤体内的运移与吸附,其效果随浓度升高而增大。润湿过程呈现三阶段特征,即水分在中大孔中的初始储存、向微小孔的运移吸附及最终平衡。本研究从微观层面揭示了纳米流体对高阶煤的润湿改性机制,可为改善煤层注水效果及矿井粉尘治理提供理论依据和技术支撑。

     

    Abstract: To thoroughly investigate the effect of nanofluids on the wetting characteristics of high-rank coal and to enhance the dust suppression performance of coal seam water injection technology,this study selected high-rank coal samples from the Tiandi Wangpo Coal Mine in Jincheng,Shanxi Province,and the Zhaogu No. 2 Coal Mine in Xinxiang,Henan Province. Contact angle experiments were conducted to examine the influence of SiO2 nanofluids on coal wettability. Low-field nuclear magnetic resonance (NMR) equipment was employed to perform Carr-Purcell-Meiboom-Gill (CPMG) sequence measurements on coal samples treated with SiO2 nanofluids at various mass fractions. The results indicate that the optimal improvement in coal wettability is achieved at a nanofluid mass fraction of 1. 50%. Nanofluids significantly enhance water migration and adsorption within the coal matrix,and the enhancement effect increases with increasing concentration. The wetting process exhibits a three-stage characteristic:initial water storage in mesopores and macropores,followed by migration and adsorption into micropores,and finally reaching equilibrium. This study elucidates the wetting modification mechanism of nanofluids on high-rank coal at the microscopic level,providing a theoretical basis and technical support for improving coal seam water injection effectiveness and mine dust control.

     

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