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煤对不同配比N2-CH4竞争吸附及应变特性研究

Study on competitive adsorption and strain characteristic of the coal under different N2-CH4 ratio

  • 摘要: 为明确煤层瓦斯吸附—解吸行为对注氮驱替效果的影响,开展煤对不同配比N2-CH4混合气体的吸附—解吸实验,通过煤体应变、吸附—解吸速率与孔隙压力变化来分析其吸附—解吸效果。研究结果表明:在吸附阶段,气体在初期能快速进入煤层孔隙,CH4会迅速占据吸附位置,随后吸附速率逐渐下降,增大N2的体积分数可以促进气体的扩散和吸附,从而提高吸附速率,孔隙压力逐渐下降,煤体在该过程中会经历挤压和收缩,但其在持续注气后会因吸附作用而膨胀,应变值会随着N2的体积分数增大而减小;在解吸阶段,气体受压力差作用,迅速释放,孔隙压力迅速降低,解吸速率先减小后趋于平稳,煤体先轴向膨胀后持续收缩,应变变化量与N2的体积分数成反比。

     

    Abstract: In order to investigate the impact of adsorption-desorption behavior of coal seam gas on the effectiveness of nitrogen injection and displacement, experiments were conducted using N2-CH4 gas mixtures with varying ratios. The performance of adsorption- desorption was analysed through the coal strain,adsorption-desorption rates,and changes in pore pressure. The results show that during the adsorption stage,the gas enters the pore space of coal seam quickly at the beginning. CH4 rapidly occupies the adsorption site,followed by gradually reduction in the adsorption rate. Enhancing the volume fraction of N 2 can improve the diffusion and adsorption of gas, thereby increasing the adsorption rate and gradually reducing the pore pressure. The coal is compressed and contracted throughout this process. However,it expands due to adsorption after continuous gas injection,and the strain value here is reduced with the increasing volume ratio of N2. During the desorption stage,gas is swiftly expelled under the effect of pressure gradients, causing a sharp decline in pore pressure. The desorption rate first decreases and then tends to stabilize. The coal first expands axially and then continuously contracts. The strain variation is inversely related to the volume fraction of N2.

     

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