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基于激光吸收光谱法的煤矿硫化氢检测

Detection of hydrogen sulfide in coal mine based on laser absorption spectrometry

  • 摘要: 为了精确预报煤矿井下硫化氢含量,防止硫化氢含量超标带来的危害,基于可调谐半导体激光吸收光谱技术,设计研制了一种便携式硫化氢检测仪。该仪器采用中心波长为1 590 nm的分布式反馈激光器,结合多次反射的郝里奥特长光程气体吸收池,可以满足煤矿井下0~200 mg/L硫化氢的实时检测。离线标定和实验室测试得到检测仪测量的相对误差为±2%,最快响应时间为0.5 s;通过实验室测量六盘水大湾煤矿120205采煤工作面上隅角和采空区的气体成分,结果表明,便携式硫化氢检测仪稳定可靠, 能够满足煤矿井下硫化氢预警的要求。

     

    Abstract: In order to accurately forecast the hydrogen sulfide content in underground coal mine and prevent the harm caused by the excessive hydrogen sulfide content, a portable hydrogen sulfide detector was designed and developed based on technology of Tunable Diode Laser Absorption Spectroscopy (TDLAS). The instrument adopted the Distributed Feedback Laser (DFB) with the central wavelength of 1 590 nm, combined with the multi-reflection Herriott long optical path gas absorption pool, which can meet the real-time detection of hydrogen sulfide from 0 mg/L to 200 mg/L in the underground coal mine. The relative error of the detector measured by offline calibration and laboratory test was ±2%, and the fastest response time system was 0.5 s; through the laboratory measurement of the gas composition of 120205 upper corner of coal face and goaf in Dawan Coal Mine of Liupanshui. The results show that the portable hydrogen sulfide detector is stable and reliable, and can meet the requirements of hydrogen sulfide early warning in underground coal mine.

     

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