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含钠磷酸盐对煤自燃抑制性能研究

顾亮

顾亮. 含钠磷酸盐对煤自燃抑制性能研究[J]. 矿业安全与环保, 2021, 48(4): 43-47,54. DOI: 10.19835/j.issn.1008-4495.2021.04.010
引用本文: 顾亮. 含钠磷酸盐对煤自燃抑制性能研究[J]. 矿业安全与环保, 2021, 48(4): 43-47,54. DOI: 10.19835/j.issn.1008-4495.2021.04.010
GU Liang. Study on inhibition performance of coal spontaneous combustion by sodium phosphate[J]. Mining Safety & Environmental Protection, 2021, 48(4): 43-47,54. DOI: 10.19835/j.issn.1008-4495.2021.04.010
Citation: GU Liang. Study on inhibition performance of coal spontaneous combustion by sodium phosphate[J]. Mining Safety & Environmental Protection, 2021, 48(4): 43-47,54. DOI: 10.19835/j.issn.1008-4495.2021.04.010

含钠磷酸盐对煤自燃抑制性能研究

详细信息
    作者简介:

    顾亮(1981-),男,河北保定人,学士,高级工程师,主要从事矿井"一通三防"工作。E-mail:guliang@kailuan.com.cn

  • 中图分类号: TD75

Study on inhibition performance of coal spontaneous combustion by sodium phosphate

  • 摘要: 为了探究含钠磷酸盐阻化剂对煤自燃氧化反应的抑制作用,以气煤作为实验煤样,选取磷酸二氢钠NaH2PO4和磷酸钠Na3PO4 2种含钠磷酸盐化合物制备阻化剂。采用同步热分析实验和程序升温氧化实验分析含钠磷酸盐对煤自燃过程中热失重、热释放,以及气相特性的影响。结果表明:当煤自燃达到热解温度后,Na3PO4不再具有阻化作用;NaH2PO4可显著提高煤自燃的临界温度、干裂温度、着火温度等,此外,NaH2PO4有效提高了煤自燃初始放热温度和最大释热温度,且降低了煤自燃最大释热功率和放热量;NaH2PO4能够提高煤自燃过程中CO、CO2及各烃类气体的初始生成温度,削弱其释放强度,其阻化率可达65.4%;相比于Na3PO4阻化剂,NaH2PO4阻化剂具有更好的阻化效果,且在煤自燃氧化全过程中均发挥了抑制作用。
    Abstract: In order to explore the inhibiting effect of sodium phosphate inhibitors on spontaneous combustion oxidation of coal, taking gas coal as the experimental coal sample, two types of sodium phosphate (NaH2PO4 and Na3PO4) were selected to prepare inhibitors. By synchronous thermal analysis experiment and programmed temperature-rise oxidation experiment, the effects of sodium phosphate on the characteristics of thermal weight loss, thermal release and gas phase during coal spontaneous combustion were analyzed.The results show that Na3PO4 no longer has resistance when the spontaneous combustion of coal reaches the pyrolysis temperature; NaH2PO4 significantly improves the critical temperature, dry crack temperature and ignition temperature of coal spontaneous combustion, in addition, NaH2PO4 not only effectively increases the initial exothermic temperature and maximum exothermic temperature, but also reduces the maximum exothermic power and heat release of coal spontaneous combustion; NaH2PO4 improves the initial generation temperature of CO, CO2 and hydrocarbon gases during coal spontaneous combustion and weakens its release intensity, its resistance rate reaches 65.4%; compared with Na3PO4 inhibitor, NaH2PO4 inhibitor has better inhibiting effect and plays an inhibitory role in the whole process of coal spontaneous combustion.
  • [1] 王德明.矿井火灾学[M].徐州:中国矿业大学出版社, 2008.
    [2]

    WANG J H, ZHANG J S, ZHU K, et al. Anatomy of explosives spontaneous combustion accidents in the Chinese underground coal mine:Causes and prevention[J]. Process Safety Progress, 2016, 35(3):221-227.

    [3] 王连聪,梁运涛,罗海珠.我国矿井热动力灾害理论研究进展与展望[J].煤炭科学技术, 2018, 46(7):1-9.
    [4] 李金亮,陆伟,王正辉,等.防止煤炭自燃的阻化机理分析[J].矿业安全与环保, 2012, 39(2):71-72.
    [5] 肖旸,吕慧菲,邓军,等.煤自燃阻化机理及其应用技术的研究进展[J].安全与环境工程, 2017, 24(1):176-182.
    [6]

    LI Q W, XIAO Y, ZHONG K Q, et al. Overview of commonly used materials for coal spontaneous combustion prevention[J]. Fuel, 2020, 275:117981.

    [7] 许红英,苗梦露,陈鹏.复合阻化剂抑制煤自燃的红外光谱实验研究[J].矿业安全与环保, 2019, 46(4):40-44.
    [8]

    LI L C, ZHENG Z Y, WANG Q Y, et al. Polyethylene as a novel low-temperature inhibitor for lignite coal[J]. Journal of Thermal Analysis and Calorimetry, 2014, 117(3):1321-1325.

    [9]

    CHENG W M, HU X M, XIE J, et al. An intelligent gel designed to control the spontaneous combustion of coal:fire prevention and extinguishing properties[J]. Fuel, 2017, 210:826-835.

    [10] 王福生,艾晴雪,赵雪琪.无机磷化合物对煤自燃的阻化作用研究[J].中国安全生产科学技术, 2017, 13(9):101-108.
    [11] 王福生,王建涛,董宪伟,等.次磷酸盐对煤自燃的阻化特性实验研究[J].煤矿安全, 2020, 51(5):45-49.
    [12] 董宪伟,艾晴雪,王福生,等.次磷酸盐阻化剂对煤结构中活性基团变化规律的影响[J].煤炭科学技术, 2016, 44(9):43-47.
    [13] 董宪伟,温志超,王福生,等.基于电子顺磁共振的煤自燃阻化剂实验研究[J].中国科技论文, 2017, 12(21):2469-2473.
    [14] 杨漪.基于氧化特性的煤自燃阻化剂机理及性能研究[D].西安:西安科技大学, 2015.
    [15]

    DENG J, YANG Y, ZHANG Y N, et al. Inhibiting effects of three commercial inhibitors in spontaneous coal combustion[J]. Energy, 2018,160:1174-1185.

    [16]

    MA L Y, WANG D M, WANG Y, et al. Synchronous thermal analyses and kinetic studies on a caged-wrapping and sustained-release type of composite inhibitor retarding the spontaneous combustion of low-rank coal[J]. Fuel Processing Technology, 2017, 157:65-75.

    [17] 张玉涛,史学强,李亚清,等.锌镁铝层状双氢氧化物对煤自燃的阻化特性[J].煤炭学报, 2017, 42(11):2892-2899.
    [18] 陆伟,王德明,陈舸,等.煤自燃阻化剂性能评价的程序升温氧化法研究[J].矿业安全与环保, 2005,32(6):12-14.
    [19] 杨朔,戴广龙,唐明云.基于程序升温的煤自燃标志气体实验研究[J].煤矿安全, 2018, 49(7):24-27.
    [20] 王福生,王建涛,顾亮,等.煤自燃预测预报多参数指标体系研究[J].中国安全生产科学技术, 2018, 14(6):45-51.
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出版历程
  • 收稿日期:  2020-07-31
  • 修回日期:  2020-07-31
  • 网络出版日期:  2022-09-16

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